The influence of non-covalent interactions on the hydrogen peroxide electrochemistry on platinum in alkaline electrolytes.
نویسندگان
چکیده
The potential range of the transition region between the diffusion-limited reduction to oxidation of hydrogen peroxide depends strongly on the nature of the cation of the supporting alkaline electrolyte. Non-covalent interactions between the hydrated alkali metal cations and chemisorbed OH species on platinum influence the potential-dependent reaction kinetics.
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ورودعنوان ژورنال:
- Chemical communications
دوره 48 53 شماره
صفحات -
تاریخ انتشار 2012